Following solutions were prepared by mixing different volumes of NaOH and HCl of different concentrations : a. 60 mL $\frac{M}{10}$ HCl + 40 mL $\frac{M}{10}$ NaOH b. 55 mL $\frac{M}{10}$ HCl + 45 mL $\frac{M}{10}$ NaOH c. 75 mL $\frac{M}{5}$ HCl + 25 mL $\frac{M}{5}$ NaOH d. 100 mL $\frac{M}{10}$ HCl + 100 mL $\frac{M}{10}$ NaOH, pH of which one of them will be equal to 1?